Qualitative Analysis – Identification of Cations using aqueous Ammonia

Qualitative Analysis – Identification of Cations using aqueous Ammonia

Qualitative Analysis is the process of identifying unknown substances in a solution.

Students are required to describe the use of aqueous sodium hydroxide and aqueous ammonia to identify the following aqueous cations: aluminium (Al3+), ammonium (NH4+), calcium (Ca2+), copper(II) (Cu2+), iron(II) (Fe2+), iron(III) (Fe3+), lead(II) (Pb2+) and zinc (Zn2+) (formulae of complex ions are not required).

We will focus on the use of aqueous ammonia in this article.

For easy memory, you may wish to first divide the cations into 2 groups – precipitate formed and no precipitate formed.

No Precipitate formed

If no precipitate is formed, we can confirm that the ion present is calcium ion.

Precipitate formed

Further divide the cations under ‘precipitate formed’ into white precipitate and coloured precipitate.

White Precipitate formed

Aluminium, zinc and lead(II) ions give white precipitate with a few drops of aqueous ammonia. If the precipitate dissolves in excess to form a colourless solution, then zinc ion is present. If the precipitate remains insoluble in excess aqueous ammonia, aluminium ion or lead(II) ions could be present. Further tests can be done to identify which of these two ions are present.

Coloured Precipitate formed

Things get easier with coloured precipitate.

Light blue precipitate is formed if copper(II) ion is present. Precipitate dissolves in excess aqueous ammonia to form a deep blue solution.

Green precipitate is formed if iron(II) ion is present. Precipitate is insoluble in excess aqueous ammonia.

Reddish brown precipitate is formed if iron(III) ion is present. Precipitate is insoluble in excess aqueous ammonia.